Rate of reaction, factors affecting rate, order and molecularity, rate laws and rate constants - One Line Questions

1. What is the instantaneous rate of reaction at time 't' for a reaction A -> Products? -d[A]/dt
2. For a first-order reaction, the integrated rate law is given by: [A]t = [A]₀ * e^(-kt)
3. For the reaction 2A + B -> C, if the rate law is Rate = k[A]^2[B]^1, what is the order of the reaction with respect to A? 2
4. What is the molecularity of a unimolecular reaction? 1
5. For the reaction R -> P, if the rate law is Rate = k[R]⁰, what is the order of the reaction? 0
6. If the half-life of a first-order reaction is 30 minutes, what is the rate constant? 0.01155 min⁻¹
7. If the rate of reaction doubles when the temperature is increased by 10°C, what is the approximate temperature coefficient? 2
8. The rate law for the reaction 2NO(g) + O₂(g) -> 2NO₂(g) is found experimentally to be Rate = k[NO]²[O₂]. What is the molecularity of this reaction? Cannot be determined from the rate law.
9. What is the order of the reaction A + B -> Products if the rate law is Rate = k[A]¹/²[B]¹? 1.5
10. What is the order of reaction with respect to reactant A if doubling the concentration of A increases the rate of reaction by a factor of 8? 3
11. For a reaction A + B -> Products, if the rate law is Rate = k[A][B]², what is the overall order of the reaction? 3
12. For a bimolecular reaction, the molecularity is: 2
13. For the reaction 2H₂ + 2NO -> 2H₂O + N₂, if the rate law is Rate = k[H₂][NO]², what is the overall order of the reaction? 3
14. The rate law for a reaction can be determined by: Experimental measurements of concentration versus time.
15. A reaction that proceeds in a single step is called: Elementary reaction
16. The Arrhenius equation relates the rate constant to: Temperature and activation energy.
17. Which of the following factors does NOT typically affect the rate of a chemical reaction? Color of the reactants
18. The rate of reaction is defined as the rate of change of: Concentration of reactants or products.
19. The rate of a reaction is generally increased by: Increasing the concentration of reactants.
20. The rate constant 'k' of a reaction is: Dependent on temperature but independent of concentration.
21. For a zero-order reaction, the rate of reaction is: Independent of the concentration of the reactant.
22. If a reaction is exothermic and the activation energy for the forward reaction is Ea(f), what is the activation energy for the reverse reaction Ea(r)? Ea(r) = Ea(f) - ΔH
23. If the rate of reaction is independent of the concentration of a reactant, it is: Zero-order with respect to that reactant.
24. The collision theory states that for a reaction to occur, reactant molecules must: Collide with sufficient kinetic energy and proper orientation.
25. A catalyst increases the rate of reaction by: Decreasing the activation energy.
26. For a first-order reaction, the half-life (t₁/₂) is: Independent of the initial concentration.
27. Which type of catalyst increases the rate of a reaction? Positive catalyst
28. Which of the following statements is true about molecularity? It is always an integer and usually less than or equal to 3.
29. What is the relationship between the rate constant (k) and temperature (T) described by the Arrhenius equation? k = A * exp(-Ea/RT)
30. Which of the following units for the rate constant 'k' indicates a third-order reaction? M⁻² s⁻¹
31. Which of the following is NOT a unit of rate of reaction? mol⁻¹ L s⁻¹
32. Which of the following statements about order and molecularity is correct? Order is determined experimentally, while molecularity is theoretical.
33. Which of the following factors has the most significant effect on the rate of a chemical reaction? Activation energy
34. The rate of a reaction is defined as the rate of disappearance of a reactant or the rate of appearance of a product. For the reaction A -> B, this can be written as: Rate = -d[A]/dt = +d[B]/dt
35. What is the unit of the rate constant (k) for a zero-order reaction? mol L⁻¹ s⁻¹
36. For a second-order reaction, the unit of the rate constant (k) is: L mol⁻¹ s⁻¹
37. The unit of the rate constant (k) for a third-order reaction is: L² mol⁻² s⁻¹
38. What is the unit of the rate constant for a first-order reaction? s⁻¹
39. What is the effect of a catalyst on the equilibrium position of a reversible reaction? Does not affect it.
40. The term 'rate-determining step' refers to: The slowest step in a reaction mechanism.
41. For a complex reaction, the rate of reaction is determined by: The slowest step (rate-determining step).
42. The activation energy (Ea) of a reaction is: The minimum energy required for reactants to form products.
43. Molecularity of a reaction is defined as: The number of molecules that collide simultaneously with proper energy and orientation to cause a reaction.
44. The rate law of a reaction provides information about: The dependence of the reaction rate on the concentration of reactants.
45. What happens to the rate of reaction if the concentration of a reactant involved in a zero-order reaction is doubled? The rate remains unchanged.
46. The rate constant of a reaction decreases as the temperature increases. This implies: The reaction is exothermic with a high activation energy.
47. The rate of a reaction is proportional to the frequency of effective collisions between reactant molecules. This statement is part of: Collision theory
48. Which of the following is a characteristic of elementary reactions? Their molecularity is equal to their order.
49. If the rate of reaction is directly proportional to the concentration of a reactant, it is said to be: First-order with respect to that reactant.